A study of PbF2 nanoparticles crystallization mechanism in mixed oxyde-fluoride glasses

TL;DR

This study investigates how varying concentrations of rare-earth ions in oxyfluoride glasses influence nanoparticle growth, crystallization, and luminescence properties, revealing the formation of crystalline PbF2:Tm-Ho phases and their potential for up-conversion luminescence.

Contribution

It provides new insights into the crystallization mechanism of PbF2 nanoparticles in oxyfluoride glasses with rare-earth ions, highlighting the effects of ion concentration on nanoparticle size and phase formation.

Findings

Increased Ho2O3 and Tm2O3 concentrations lead to larger nanoparticles.

High concentrations induce crystalline PbF2:Tm-Ho phase formation.

Nanoparticle morphology remains unaffected by rare-earth ion concentration.

Abstract

The heat-treated oxyfluoride glasses with different contents of thulium Tm3+ and holmium Ho3+ ions have been studied using small-angle X-ray scattering and diffraction. With an increase in relative concentration of added Ho2O3 and Tm2O3 oxides, the growing in the average size of both nanoparticles and local density fluctuations in the glass matrix is observed. In addition, at high relative concentrations of initial rare-earth oxides, the appearance of a crystalline cubic phase PbF2:Tm-Ho is observed, which can provide a source of up-conversion luminescence in the studied glass materials. A change in the concentration of the initial Ho2O3 and Tm2O3 oxides does not effect on a morphology and fractal dimension of the formed luminescence nanoparticles. The structural aspects of nanoparticle formation with up-conversion luminescence phenomenon are discussed.