Microstructure Evolution of Solid Oxide Fuel Cell Anodes Characterized by Persistent Homology

TL;DR

This paper introduces a novel method combining electron tomography and persistent homology to analyze three-dimensional microstructure evolution in solid oxide fuel cell anodes, revealing new insights into degradation mechanisms.

Contribution

It presents an innovative approach using topological data analysis to study microstructural changes in fuel cell electrodes over long-term operation.

Findings

Identified microstructural degradation patterns in nickel, pores, and zirconium phases.

Provided new topological insights into the degradation process.

Demonstrated the effectiveness of persistent homology in microstructure analysis.

Abstract

Uncovering microstructure evolution mechanisms that accompany the long-term operation of solid oxide fuel cells is a fundamental challenge in designing a more durable energy system for the future. To date, the study of fuel cell stack degradation has focused mainly on electrochemical performance and, more rarely, on averaged microstructural parameters. Here we show an alternative approach in which an evolution of three-dimensional microstructural features is studied using electron tomography coupled with topological data analysis. The latter produces persistent images of microstructure before and after long-term operation of electrodes. Those images unveil a new insight into the degradation process of three involved phases: nickel, pores, and yttrium-stabilized zirconium.