Critical splay fluctuations and colossal flexoelectric effect above non-polar to polar nematic phase transition

TL;DR

This study investigates the pretransitional splay fluctuations and colossal flexoelectric effect in polar nematic liquid crystals, revealing strong coupling between fluctuations and electric polarization near the phase transition.

Contribution

It provides experimental evidence of splay fluctuation influence on birefringence and flexoelectricity above the phase transition, advancing understanding of ferroelectric nematic properties.

Findings

Splay fluctuations affect birefringence above the transition temperature.

Flexoelectric coefficient exhibits a power-law dependence on temperature.

Strong coupling between splay fluctuations and polarization reduces elastic constant.

Abstract

The recent discovery of nematic liquid crystals with polar order (ferroelectric nematic) has created immense interest. Despite intensive research, several physical properties of this liquid crystal are yet to be investigated and understood. Here, we report experimental studies on the birefringence and exoelectric coefficient of a polar nematic (NF) liquid crystal. Our experiments directly reveal that the splay fluctuations influence the birefringence several degrees above the nonpolar (N) to polar-nematic (NF) phase transition temperature and the heat capacity exponent obtained from the tilt angle fluctuations is close to the value reported in adiabatic scanning calorimetry measurements. The flexoelectric coefficient of the nonpolar nematic phase shows a power-law dependence on temperature. Our results demonstrate a strong coupling of splay fluctuations with electric polarization that reduces the splay elastic constant and consequently enhances the flexoelectric coefficient. These results are important for forthcoming applications as well as for understanding all pretransitional effects in ferroelectric nematic liquid crystals.