Exotic liquid crystalline phases in monolayers of vertically vibrated granular particles

TL;DR

This paper explores exotic liquid-crystalline phases in vibrated monolayers of granular particles, revealing novel p-atic phases and topological defects, with experimental, theoretical, and simulation insights.

Contribution

It introduces experimental observations of exotic liquid-crystal phases in vibrated granular monolayers and compares them with theoretical predictions and simulations.

Findings

Identification of triatic and octatic phases in specific particle shapes.

Observation of topological defects caused by geometric frustration.

Discrepancies between experimental results and density-functional theory predictions.

Abstract

Vibrated monolayers of granular particles confined into horizontal cavities form a variety of fluid patterns with orientational order that resemble equilibrium liquid-crystal phases. In some cases one can identify nematic and smectic patters that can be understood in terms of classical statistical mechanics of hard bodies. Low aspect ratio cylinders project as rectangles and form uniaxial, or 2-atic, and tetratic, or 4-atic, nematic phases. Other polygonal particles may exhibit different liquid-crystal phases, in general $p$-atic phases, of higher symmetries. We give a brief summary of theoretical work on rectangles and triangles, and provide some experimental results on vibrated monolayers. In the case of equilateral triangles, the theory predicts an exotic triatic phase, or 6-atic phase, with six-fold symmetry and three equivalent directors. Right-angled triangles exhibit a 4-atic phase with strong octatic (8-atic) correlations. Experiments on cylinders show 4-atic textures and, even more remarkable, geometric frustration caused by confinement excites topological defects, which seem to follow the same topological rules as standard liquid crystals. Some of our findings can be understood with the help of simulations of hard particles subject to thermal equilibrium, although standard Density-Functional Theories fail to account for the correct equilibrium phases in some cases.