Photoinduced sliding transition into a hidden phase in van der Waals materials

TL;DR

This paper presents a theoretical framework for understanding photoinduced phase transitions in layered van der Waals materials, showing how light can trigger a metastable sliding transition between stacking configurations.

Contribution

It introduces a minimal bilayer model to explain how photodoping can induce a sliding transition, revealing a new mechanism for metastability in layered materials.

Findings

Photodoping can transiently destabilize the global energy minimum.

Layer sliding induces a transition from insulator to a nearly gapless phase.

Local interactions enhance the sliding effect and phase transition.

Abstract

We propose a generic scenario for metastability and excitation-induced switching in layered materials. Focusing on a minimal bilayer stack, where each layer consists of a honeycomb lattice with A and B sublattices, we map out the energy landscape with respect to the relative sliding of the layers. The sliding affects the interlayer hopping, which induces a splitting between bonding and anti-bonding bands. When this splitting is large, the AA and AB stacking configurations correspond to the global and secondary minima, respectively, and these configurations are separated by a barrier against layer-sliding. While chemical doping only flattens this barrier, strong \emph{photodoping} from bonding to antibonding bands can transiently destabilize the global minimum and induce a sliding motion toward the AB stacked configuration, thereby switching from an equilibrium insulator to a nearly gapless metastable phase. This hopping-driven effect is enhanced by local repulsive interactions, which increase the gap and facilitate the inter-layer sliding.