Submillimeter observations of molecular gas interacting with the supernova remnant W28

TL;DR

This study presents submillimeter observations of molecular gas interacting with supernova remnant W28, revealing complex molecules and physical conditions, and highlighting the chemical richness in such energetic environments.

Contribution

First detection of thermally excited CH₃OH in a supernova remnant, with detailed physical constraints derived from multi-molecule observations and non-LTE modeling.

Findings

Detection of multiple molecular species including CH₃OH and H₂CO.

Kinetic temperature constrained between 60 and 100 K.

Gas density estimated from 9×10⁵ to 5×10⁶ cm⁻³.

Abstract

Context: Supernovae (SNe) inject large amounts of energy and chemically enriched materials into their surrounding interstellar medium and, in some instances, into molecular clouds (MCs). The interaction of a supernova remnant (SNR) with a MC plays a crucial role in the evolution of the cloud's physical and chemical properties. Despite their importance, only a handful of studies have been made addressing the molecular richness in MCs impacted by SNRs. (Sub)millimter wavelength observations of SNR-MC can be used to build a census of their molecular richness, which in turn can motivate various chemical and physical models aimed at explaining the chemical evolution of the clouds. Aims: We carried out multi-molecule/multi-transition observations toward the region F abutting the SNR W28. We used the detected lines to constrain the physical conditions of this region. Methods: We used the APEX Telescope to observe molecular lines in the frequency from $213\rm{-}374\, \textrm{GHz}$. We used non-LTE RADEX modeling to interpret the observational data. Results: We detected emission from multiple molecular species, namely CH$_{3}$OH, H$_{2}$CO, SO, SiO, CN, CCH, NO, CS, HCO$^+$, HCN, HNC, N$_2$H$^+$, CO, and from isotopologues of some of them. We report the first detection of thermally excited (non-maser) CH$_{3}$OH emission toward a SNR. Employing non-LTE RADEX modeling of multiple H$_{2}$CO and CH$_{3}$OH lines, we constrain the kinetic temperature from 60 to 100$\,$K and the gas density from $9\times 10^{5}$ to $5\times 10^{6}\,\rm cm^{-3}$. We obtained an ortho-para ratio $\sim$2 for H$_{2}$CO, which indicates that formaldehyde is most likely formed on dust grain surfaces. Conclusions: Our results show that molecules as complex as H$_{2}$CO and CH$_{3}$OH can be detected in SNR-MC interactions. This could motivate chemical modelling to explore their formation pathways.