Static and dynamic magnetic properties of the spin-5/2 triangle lattice antiferromagnet Na3Fe(PO4)2 studied by 31P NMR

TL;DR

This study uses $^{31}$P NMR to investigate the magnetic properties and spin dynamics of a spin-5/2 triangular lattice antiferromagnet Na$_3$Fe(PO$_4$)$_2$, revealing a conventional 3D antiferromagnetic ground state without significant frustration effects.

Contribution

First detailed NMR analysis of Na$_3$Fe(PO$_4$)$_2$ revealing its magnetic transition, exchange interactions, and spin dynamics in a spin-5/2 triangular lattice antiferromagnet.

Findings

Antiferromagnetic transition at $T_N=10.9$ K confirmed by NMR.

Exchange coupling estimated as $J/k_B \,\simeq\, 1.9$ K.

Ground state is a conventional 3D antiferromagnet with no significant frustration.

Abstract

$^{31}$P nuclear magnetic resonance (NMR) measurements have been carried out to investigate the magnetic properties and spin dynamics of Fe$^{3+}$ ($S$ = 5/2) spins in the two-dimensional triangular lattice (TL) compound Na$_3$Fe(PO$_4$)$_2$. The temperature ($T$) dependence of nuclear spin-lattice relaxation rates ($1/T_1$) shows a clear peak around N\'eel temperature, $T_{\rm N} = 10.9$~K, corresponding to an antiferromagnetic (AFM) transition. From the temparature dependence of NMR shift ($K$) above $T_{\rm N}$, an exchange coupling between Fe$^{3+}$ spins was estimated to be $J/k_{\rm B}\simeq 1.9$~K using the spin-5/2 Heisenberg isotropic-TL model. The temperature dependence of $1/T_1T$ divided by the magnetic susceptibility ($\chi$), $1/T_1T\chi$, above $T_{\rm N}$ proves the AFM nature of spin fluctuations below $\sim$ 50 K in the paramagnetic state. In the magnetically ordered state below $T_{\rm N}$, the characteristic rectangular shape of the NMR spectra is observed, indicative of a commensurate AFM state in its ground state. The strong temperature dependence of 1/$T_1$ in the AFM state is well explained by the two-magnon (Raman) process of the spin waves in a 3D antiferromagnet with a spin-anisotropy energy gap of 5.7 K. The temperature dependence of sublattice magnetization is also well reproduced by the spin waves. Those results indicate that the magnetically ordered state of Na$_3$Fe(PO$_4$)$_2$ is a conventional 3D AFM state, and no obvious spin frustration effects were detected in its ground state.