Effect of nano-size on magnetostriction of BiFeO3 and exceptional magnetoelectric coupling properties of BiFeO3_P(VDF-TrFE) polymer composite films for magnetic field sensor application

TL;DR

This study demonstrates room-temperature magnetostriction in superparamagnetic BiFeO3 nanoparticles and high magnetoelectric coupling in BiFeO3_P(VDF-TrFE) nanocomposites, highlighting their potential for magnetic sensors and spintronic devices.

Contribution

It provides direct evidence of magnetostriction in nano BiFeO3 and reports high magnetoelectric coupling in nanocomposites, advancing applications in magnetic sensing.

Findings

Magnetostrictive strain observed in superparamagnetic BiFeO3 nanoparticles.

High magnetoelectric coupling coefficient in BiFeO3_P(VDF-TrFE) nanocomposites.

Room-temperature multiferroic properties demonstrated in the nanocomposite films.

Abstract

The existence of magnetostriction in bulk BiFeO3 is still a matter of investigation and it is also an issue to investigate the magnetostriction effect in nano BiFeO3. Present work demonstrates the existence of magnetostrictive strain in superparamagnetic BiFeO3 nanoparticles at room temperature and the magnetoelectric coupling properties in composite form with P(VDFTrFE). Despite few reports on the magnetostriction effect in bulk BiFeO3 evidenced by the indirect method, the direct method (strain gauge) was employed in this work to examine the magnetostriction of superparamagnetic BiFeO3. In addition, a high magnetoelectric coupling coefficient was observed by the lock-in technique for optimized BiFeO3_P(VDF-TrFE) nanocomposite film. These nanocomposite films also exhibit room-temperature multiferroic properties. These results provide aspects of material with immense potential for practical applications in spintronics and magneto-electronics applications. We report a magnetoelectric sensor using superparamagnetic BiFeO3_P(VDF-TrFE) nanocomposite film for detection of ac magnetic field.