Classical limit of Gibbs states for quantum spin systems
Heinz-J\"urgen Schmidt

TL;DR
This paper investigates how quantum Gibbs states of spin systems transition to classical Gibbs states as the spin quantum number grows large, using polynomial approximations and phase space analysis.
Contribution
It introduces a method to analyze the classical limit of quantum Gibbs states for spin systems via polynomial approximation and phase space functions.
Findings
Convergence of quantum to classical Gibbs states demonstrated
Explicit calculation of spin monomials in phase space
Application to the Heisenberg dimer example
Abstract
We study the relation between quantum mechanical and classical Gibbs states of spin systems with spin quantum number . It is known that quantum states and observables can be represented by functions defined on the phase space , which in our case is the -fold product of unit spheres. Therefore, the classical limit of (suitably scaled) quantum Gibbs states can be described as the limit of functions defined on . We choose to approximate the exponential function of the Hamiltonian by a polynomial of degree and thus have to deal with the problem of the limit of double sequences (depending on and ) treated in the theorem of Moore-Osgood. The convergence of quantum Gibbs states to classical ones is illustrated by the example of the Heisenberg dimer. We apply our method to the explicit calculation of the phase space function describing…
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Taxonomy
TopicsAdvanced Thermodynamics and Statistical Mechanics · Spectroscopy and Quantum Chemical Studies · Statistical Mechanics and Entropy
