The criterion of planar instability in alloy solidification under varying conditions: A viewpoint from free energy

TL;DR

This paper investigates the criteria for planar instability in alloy solidification under varying conditions, emphasizing the roles of free energy and interfacial energy through theoretical and phase-field models, validated by simulations.

Contribution

It introduces a new criterion based on excess free energy and interfacial energy for planar instability in alloy solidification, considering varying conditions and crystallographic orientations.

Findings

Good agreement between phase-field and theoretical models.

Excess free energy and interfacial energy significantly influence instability.

Orientation affects the instability mechanism.

Abstract

In alloy solidification, the transport processes of heat and solute result in morphological instability of the interface, forming different patterns of solidification structure and determining the mechanical properties of components. As the first observable phenomenon of the morphological instabilities, the planar instability influences the subsequent stages significantly, deserving in-depth investigations. In this paper, the planar instability in alloy solidification under varying conditions is studied. Firstly, the dynamical evolution of the planar instability is performed by the theoretical model and phase-field model, respectively. Secondly, to represent the history-dependence of solidification, the varying parameters are adopted in the simulations. Then the criterion of the planar instability under the varying conditions is discussed. This paper considers the critical parameters of the planar instability are the excess free energy at the interface and corresponding interfacial energy. Finally, to validate the criterion, the comparisons between the phase-field model and theoretical model are carried out, showing good consistency. Moreover, solidification processes with different preferred crystallographic orientations are performed, demonstrating the effect mechanism of the excess free energy and interfacial energy on the planar instability. The idea of the interfacial energy influencing the planar instability could be applied to investigating other patterns induced by interfacial instability.