Real-space Observation of Unidirectional Charge Density Wave and Complex Structural Modulation in the Pnictide Superconductor Ba$_{1-x}$Sr$_x$Ni$_2$As$_2$

TL;DR

This study uses scanning tunneling microscopy to reveal unidirectional charge density waves and structural modulations in Ba$_{1-x}$Sr$_x$Ni$_2$As$_2$, elucidating their relationship with superconductivity across different phases.

Contribution

It provides the first real-space observation of unidirectional CDW and structural modulations in this pnictide superconductor, highlighting the effects of Sr substitution on these phenomena.

Findings

Unidirectional CDW observed in low-temperature triclinic phase.

Sr substitution suppresses CDW and stabilizes superstructures.

Superconductivity is enhanced with Sr substitution.

Abstract

Here we use low-temperature and variable-temperature scanning tunneling microscopy to study the pnictide superconductor, Ba$_{1-x}$Sr$_x$Ni$_2$As$_2$. In the low-temperature phase (triclinic phase) of BaNi$_2$As$_2$, we observe the unidirectional charge density wave (CDW) with $Q$ = 1/3 on both the Ba and NiAs surfaces. On the NiAs surface of the triclinic BaNi$_2$As$_2$, there are structural-modulation-induced chain-like superstructures with distinct periodicities. In the high-temperature phase (tetragonal phase) of BaNi$_2$As$_2$, the NiAs surface appears as the periodic 1 by 2 superstructure. Interestingly, in the triclinic phase of Ba$_{0.5}$Sr$_{0.5}$Ni$_2$As$_2$, the unidirectional CDW is suppressed on both the Ba/Sr and NiAs surfaces, and the Sr substitution stabilizes the periodic 1 by 2 superstructure on the NiAs surface, which enhance the superconductivity in Ba$_{0.5}$Sr$_{0.5}$Ni$_2$As$_2$. Our results provide important microscopic insights for the interplay among the unidirectional CDW, structural modulation, and superconductivity in this class of pnictide superconductors.