Dual origin of viscoelasticity in polymer-carbon black hydrogels: a rheometry and electrical spectroscopy study

TL;DR

This study reveals two distinct viscoelastic behaviors in polymer-carbon black hydrogels, linked to their microstructure and electrical properties, with implications for designing nanocomposites with tailored functionalities.

Contribution

It uncovers the dual origin of viscoelasticity in CB-CMC hydrogels and links mechanical and electrical properties to microstructure and concentration ratios.

Findings

Low CMC: electrically conductive, glassy viscoelastic spectrum, percolated CB network.

High CMC: non-conductive, isolated CB clusters, mechanical rigidity from CB as crosslinkers.

Power-law viscoelastic spectra follow Zimm theory, dependent on CMC concentration.

Abstract

Nanocomposites formed by mixing nanoparticles and polymers offer a limitless creative space for the design of functional advanced materials with a broad range of applications in materials and biological sciences. Here we focus on aqueous dispersions of hydrophobic colloidal soot particles, namely carbon black (CB) dispersed with a sodium salt of carboxymethylcellulose (CMC), a food additive known as cellulose gum that bears hydrophobic groups, which are liable to bind physically to CB particles. Varying the relative content of CB nanoparticles and cellulose gum allows us to explore a rich phase diagram that includes a gel phase. We investigate this hydrogel using rheometry and electrochemical impedance spectroscopy. CB-CMC hydrogels display two radically different types of mechanical behaviors that are separated by a critical CMC-to-CB mass ratio $r_c$. For $r<r_c$, i.e., for low CMC concentration, the gel is electrically conductive and shows a glassy-like viscoelastic spectrum, pointing to a microstructure composed of a percolated network of CB nanoparticles decorated by CMC. In contrast, gels with CMC concentration larger than $r_c$ are non-conductive, indicating that the CB nanoparticles are dispersed in the cellulose gum matrix as isolated clusters, and act as physical crosslinkers of the CMC network, hence providing mechanical rigidity to the composite. Moreover, in the concentration range, $r>r_c$ CB-CMC gels display a power-law viscoelastic spectrum that depends strongly on the CMC concentration. These relaxation spectra can be rescaled onto a master curve that exhibits a power-law scaling in the high-frequency limit, with an exponent that follows Zimm theory, showing that CMC plays a key role in the gel viscoelastic properties for $r>r_c$. Our results offer a characterization of CB-CMC dispersions that will be useful for designing nanocomposites based on hydrophobic interactions.