Fundamental Investigation of Reactive-Convective Transport: Implications for Long-Term Carbon dioxide (CO2) Sequestration

TL;DR

This study visualizes and analyzes the mechanisms of density-driven convective transport of CO2 in saline aquifers, revealing how salts, flow conditions, and heterogeneities influence dissolution rates and flow patterns relevant to long-term sequestration.

Contribution

It provides experimental insights into the effects of salts, flow rates, and heterogeneities on CO2 convection and dissolution, advancing understanding of long-term storage processes.

Findings

Salts cause earlier convection onset and larger finger wavelengths.

Dipping enhances lateral mixing of CO2 fingers.

Salt presence reduces CO2 dissolution rate but increases diffusive flux.

Abstract

The density-driven convection coupled with chemical reaction is the preferred mechanism for permanently storing CO2 in saline aquifers. This study uses a 2D visual Hele-Shaw cell to evaluate and visualize the density-driven convection formed due to gravitational instabilities, also known as Rayleigh-Taylor instability. The primary goal of the experiments is to understand the various mechanisms for the mass transfer of gaseous CO2 into brine with different initial ionic concentrations and flow permeability. Moreover, the impact of CO2 flow rates, injection locations, reservoir dipping angle, and permeability heterogeneity is also investigated. We observed that the presence of salts resulted in earlier onset of convection and a larger convective finger wavelength than the case with no dissolved salts. In addition, experimental data showed a higher lateral mixing between CO2 fingers when dipping is involved. The visual investigation also revealed that the CO2 dissolution rate, measured by the rate of the convective fingers advance, depends on the type and concentration of the ions present in the brine. The CO2 dissolution for solutions with varying salt dissolved, indicated by the area of the pH-depressed region, is observed to be 0.38-0.77 times compared to when no salt is present. Although convective flow is slowed down in the presence of salts, the diffusive flux is enhanced, as observed from both qualitative and quantitative results. Moreover, the reduced formation permeability, introduced by using a flow barrier, resulted in numerous regions not being swept by the dissolved CO2, indicating an inefficient dissolution. We also investigated the effect of discrete high conductivity fractures within the flow barriers, which showed an uneven vertical sweep and enhanced flow channeling. Lastly, the parameters regarding CO2 leakage risk during storage are identified and discussed.