Energetic Electron Irradiations of Amorphous and Crystalline Sulphur-Bearing Astrochemical Ices

TL;DR

This study investigates how the solid phase (amorphous or crystalline) of sulphur-bearing astrochemical ices affects their radiolytic decay under energetic electron irradiation, revealing phase-dependent chemical stability relevant to astrochemistry.

Contribution

It extends previous work by comparing energetic electron irradiation effects on amorphous and crystalline H2S and SO2 ices at 20 K, highlighting phase-dependent chemical decay behaviors.

Findings

Amorphous H2S decays faster than crystalline H2S under irradiation.

Crystalline SO2 shows rapid decay at low fluence, while amorphous SO2 resists decay.

Both phases of SO2 decay slowly at high fluence.

Abstract

Laboratory experiments have confirmed that the radiolytic decay rate of astrochemical ice analogues is dependent upon the solid phase of the target ice, with some crystalline molecular ices being more radio-resistant than their amorphous counterparts. The degree of radio-resistance exhibited by crystalline ice phases is dependent upon the nature, strength, and extent of the intermolecular interactions that characterise their solid structure. For example, it has been shown that crystalline CH3OH decays at a significantly slower rate when irradiated by 2 keV electrons at 20 K than does the amorphous phase due to the stabilising effect imparted by the presence of an extensive array of strong hydrogen bonds. These results have important consequences for the astrochemistry of interstellar ices and outer Solar System bodies, as they imply that the chemical products arising from the irradiation of amorphous ices (which may include prebiotic molecules relevant to biology) should be more abundant than those arising from similar irradiations of crystalline phases. In this present study, we have extended our work on this subject by performing comparative energetic electron irradiations of the amorphous and crystalline phases of the sulphur-bearing molecules H2S and SO2 at 20 K. We have found evidence for phase-dependent chemistry in both these species, with the radiation-induced exponential decay of amorphous H2S being more rapid than that of the crystalline phase, similar to the effect that has been previously observed for CH3OH. For SO2, two fluence regimes are apparent: a low-fluence regime in which the crystalline ice exhibits a rapid exponential decay while the amorphous ice possibly resists decay, and a high-fluence regime in which both phases undergo slow exponential-like decays.