Influence of oscillatory shear on nucleation in metallic glasses: a molecular dynamics study

TL;DR

This study uses molecular dynamics simulations to explore how oscillatory shear influences nucleation in metallic glasses, revealing that elastic stress controls TTT curves and can enhance forming while suppressing nucleation.

Contribution

It provides a quantitative model for the effect of oscillatory shear on nucleation, highlighting the role of elastic stress and decoupling mobility from nucleation in metallic glasses.

Findings

Elastic stress, not strain rate, controls TTT curve evolution.

Oscillatory loading can suppress nucleation while enhancing mobility.

The shortest incubation time remains unaffected by external loading.

Abstract

The process of crystal nucleation can be accelerated or retarded by ultrasonic vibration, which is particularly attractive for the addictive manufacture and thermoplastic forming of metallic glasses, however, the effect and mechanism of oscillatory loading on the nucleation process are still elusive. By using molecular dynamics simulation, the changes in the time-temperature-transformation (TTT) curve under oscillatory external loading are systematically investigated in two typical binary alloys. A glass forming ability dependent response to the external loading is found, and the shortest incubation time is insensitive to the external loading, while the corresponding temperature can be significantly shifted. Within the framework of classical nucleation theory, a fitting formula is proposed to describe the simulation data quantitatively. In contrast to stationary shear, the elastic stress, rather than the strain rate, is the key parameter to control the evolution of TTT curve under oscillatory loading. Furthermore, the model shows that oscillatory loading can decouple the mobility and nucleation in the deeply supercooled liquid, hence the formation ability can be enhanced while the nucleation is suppressed, which is particularly helpful for the forming and manufacturing of metallic glasses.