The asymptotic emergence of the Second Law for a repeated charging process

TL;DR

This paper formulates a quantum version of the Second Law based on the asymptotic properties of repeated charging processes, emphasizing the role of passive states and Markov chain theory.

Contribution

It introduces a novel quantum formulation of the Second Law using asymptotic analysis and passive states, supported by Markov chain classification.

Findings

Ergotropy can increase indefinitely with non-passive states.

Passive states generalize the concept of heat baths in quantum thermodynamics.

Asymptotic behavior distinguishes energy and ergotropy growth via Markov chain types.

Abstract

In one of its versions, the Second Law states: "It is impossible to construct an engine which will work in a complete cycle, and produces no effect except the raising of a weight and cooling of a heat reservoir." While the Second Law is considered as one of the most robust laws of Nature, it is still challenging how to interpret it in a fully quantum domain. Here we unpack the true meaning of the "cyclicity" and formulate the Second Law for a generic quantum battery via its asymptotic properties of a charging process rather than in terms of a single cycle. As a paradigm, we propose a machine consisting of a battery that repeatedly interacts with identically prepared systems. We then propose the Second Law in the form: The ergotropy of the battery may increase indefinitely if and only if systems are in a non-passive state. One of the most interesting features of this new formulation is the appearance of the passive states that naturally generalize the notion of the heat bath. In this paper, we provide a handful of results that supports this formulation for diagonal systems. Interestingly, our methodology meets a well-known theory of Markov chains, according to which we classify the general charging processes based on the passivity/non-passivity of charging systems. In particular, the adopted mathematics allows us to distinguish a subtle asymptotic difference between the indefinite increase of the battery's energy (induced by the maximally mixed states) and of ergotropy (induced by the non-passive states) in terms of the so-called null-recurrent versus transient Markov chains.