Experimental determination of the dissociative recombination rate coefficient for rotationally-cold CH$^{+}$ and its implications for the diffuse cloud chemistry

TL;DR

This study precisely measures the dissociative recombination rate of CH$^+$ ions, significantly reducing uncertainty and enhancing the accuracy of diffuse cloud chemistry models used in astrophysics.

Contribution

The paper provides the first accurate experimental determination of the CH$^+$ dissociative recombination rate coefficient applicable across diffuse cloud conditions.

Findings

Reduces uncertainty in CH$^+$ DR rate to ~20%.

DR is a significant destruction mechanism in diffuse clouds.

Applicable across temperatures from quiescent to shock-heated gas.

Abstract

Observations of CH$^+$ are used to trace the physical properties of diffuse clouds, but this requires an accurate understanding of the underlying CH$^+$ chemistry. Until this work, the most uncertain reaction in that chemistry was dissociative recombination (DR) of CH$^+$. Using an electron-ion merged-beams experiment at the Cryogenic Storage Ring, we have determined the DR rate coefficient of the CH$^+$ electronic, vibrational, and rotational ground state applicable for different diffuse cloud conditions. Our results reduce the previously unrecognized order-of-magnitude uncertainty in the CH$^+$ DR rate coefficient to $\sim \pm 20\%$ and are applicable at all temperatures relevant to diffuse clouds, ranging from quiescent gas to gas locally heated by processes such as shocks and turbulence. Based on a simple chemical network, we find that DR can be an important destruction mechanism at temperatures relevant to quiescent gas. As the temperature increases locally, DR can continue to be important up to temperatures of $ \sim 600\,\mathrm{K} $ if there is also a corresponding increase in the electron fraction of the gas. Our new CH$^+$ DR rate coefficient data will increase the reliability of future studies of diffuse cloud physical properties via CH$^+$ abundance observations.