The formation of CO$_2$ through consumption of gas-phase CO on vacuum-UV irradiated water ice

TL;DR

This study experimentally demonstrates that gas-phase CO reacts with solid-state OH radicals on water ice under UV irradiation, forming CO$_2$, which could explain CO depletion in protoplanetary disks and the presence of CO$_2$ in interstellar ices.

Contribution

It provides new experimental evidence of CO reacting with OH radicals on water ice, revealing a lower water ice dissociation efficiency and its implications for astrochemical models.

Findings

Gas-phase CO converts to CO$_2$ with 7-27% efficiency.

CO$_2$ remains in solid state between 40-60 K, then released at higher temperatures.

Water ice dissociation efficiency is lower than previously assumed.

Abstract

[Abridged] Observations of protoplanetary disks suggest that they are depleted in gas-phase CO. It has been posed that gas-phase CO is chemically consumed and converted into less volatile species through gas-grain processes. Observations of interstellar ices reveal a CO$_2$ component within H$_2$O ice suggesting co-formation. The aim of this work is to experimentally verify the interaction of gas-phase CO with solid-state OH radicals above the sublimation temperature of CO. Amorphous solid water (ASW) is deposited at 15 K and followed by vacuum-UV (VUV) irradiation to dissociate H$_2$O and create OH radicals. Gas-phase CO is simultaneously admitted and only adsorbs with a short residence time on the ASW. Products in the solid state are studied with infrared spectroscopy and once released into the gas phase with mass spectrometry. Results show that gas-phase CO is converted into CO$_2$, with an efficiency of 7-27%, when interacting with VUV irradiated ASW. Between 40 and 90 K, CO$_2$ production is constant, above 90 K, O$_2$ production takes over. In the temperature range of 40-60 K, the CO$_2$ remains in the solid state, while at temperatures $\geq$ 70 K the formed CO$_2$ is released into the gas phase. We conclude that gas-phase CO reacts with solid-state OH radicals above its sublimation temperature. This gas-phase CO and solid-state OH radical interaction could explain the observed CO$_2$ embedded in water-rich ices. It may also contribute to the observed lack of gas-phase CO in planet-forming disks, as previously suggested. Our experiments indicate a lower water ice dissociation efficiency than originally adopted in model descriptions of planet-forming disks and molecular clouds. Incorporation of the reduced water ice dissociation and increased binding energy of CO on a water ice surfaces in these models would allow investigation of this gas-grain interaction to its full extend.