Master Curves for FENE-P Fluids in Steady Shear Flow

TL;DR

This paper develops universal master curves for FENE-P fluid rheology in steady shear flow, revealing how finite extensibility influences shear-thinning behavior and matching experimental data across different polymer solutions.

Contribution

It introduces a method to evaluate steady material functions and constructs universal master curves based on the Weissenberg number and finite extensibility, enhancing understanding of nonlinear polymer flow behavior.

Findings

Universal master curves for shear stress and normal stress difference.

Steady shear experiments confirm the master curves.

Finite extensibility dominates at high shear rates.

Abstract

The FENE-P (Finitely-Extensible Nonlinear Elastic) dumbbell constitutive equation is widely used in simulations and stability analyses of free and wall-bounded viscoelastic shear flows due to its relative simplicity and accuracy in predicting macroscopic properties of dilute polymer solutions. The model contains three independent material parameters, which expressed in dimensionless form correspond to a Weissenberg number ($\textrm{Wi}$), i.e., the ratio of the dumbbell relaxation time scale to a characteristic flow time scale, a finite extensibility parameter ($L$), corresponding to the ratio of the fully extended dumbbell length to the root mean square end-to-end separation of the polymer chain under equilibrium conditions, and a solvent viscosity ratio, commonly denoted $\beta$. An exact solution for the rheological predictions of the FENE-P model in steady simple shear flow is available [Sureshkumar et al., Phys Fluids (1997)], but the resulting nonlinear and nested set of equations do not readily reveal the key shear-thinning physics that dominates at high $\textrm{Wi}$ as a result of the finite extensibility of the polymer chain. In this note we review a simple way of evaluating the steady material functions characterizing the nonlinear evolution of the polymeric contributions to the shear stress and first normal stress difference as the shear rate increases, provide asymptotic expansions as a function of $\textrm{Wi}$ , and show that it is in fact possible to construct universal master curves for these two material functions as well as the corresponding stress ratio. Steady shear flow experiments on three highly elastic dilute polymer solutions of different finite extensibilities also follow the identified master curves. The governing dimensionless parameter for these master curves is $\textrm{Wi}/L$ and it is only in strong shear flows exceeding $\textrm{Wi}/L \gtrsim 1$ that the effects of finite extensibility of the polymer chains dominate the evolution of polymeric stresses in the flow field. We suggest that reporting the magnitude of $\textrm{Wi}/L$ when performing stability analyses or simulating shear-dominated flows with the FENE-P model will help clarify finite extensibility effects.