Molecular-orbital representation with random U(1) variables
Tomonari Mizoguchi, Yasuhiro Hatsugai

TL;DR
This paper introduces a new class of random tight-binding models using molecular-orbital representation with U(1) variables, revealing unique spectral properties and critical states in the unitary class.
Contribution
It presents a novel molecular-orbital based random model with U(1) variables, demonstrating distinct spectral gaps and critical states not seen in real-valued models.
Findings
Finite energy gap opens on top of zero energy modes.
Band center of finite energy modes is critical.
Constructs models with critical states on composite lattices.
Abstract
We propose random tight-binding models that host macroscopically degenerate zero energy modes and belong to the unitary class. Specifically, we employ the molecular-orbital representation, where a Hamiltonian is constructed by a set of non-orthogonal orbitals composed of linear combinations of atomic orbitals. By setting the coefficients appearing in molecular orbitals to be random U(1) variables, we can make the models belong to the unitary class. We find two characteristic behaviors that are distinct from the random-real-valued molecular-orbital model. Firstly, a finite energy gap opens on top of the degenerate zero energy modes. Secondly, besides the zero energy modes, we also argue that the band center of the finite energy modes is critical, which is inherited from the dual counterpart, namely, the random-phase model on a bipartite lattice. Furthermore, as a by-product of this…
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Taxonomy
TopicsSurface Chemistry and Catalysis · Machine Learning in Materials Science · Advanced Chemical Physics Studies
