Minimum Surfactant Concentration Required for Inducing Self-shaping of Oil Droplets and Competitive Adsorption Effects

TL;DR

This study identifies the minimum surfactant concentration needed to induce self-shaping in oil droplets, revealing that it is approximately equal to the CMC, and explores competitive adsorption effects in mixed surfactant systems.

Contribution

It systematically investigates the minimum effective surfactant concentration for oil droplet shaping and elucidates competitive adsorption effects in mixed surfactant systems.

Findings

Minimum effective concentration is near the CMC or solubility limit.

Low stability of emulsions near the CMC.

A ~75% surface coverage of shape-inducing surfactant is necessary for self-shaping.

Abstract

Surfactant choice is key in starting the phenomena of artificial morphogenesis, the bottom-up growth of geometric particles from cooled emulsion droplets, as well as the bottom-up self-assembly of rechargeable microswimmer robots from similar droplets. The choice of surfactant is crucial for the formation of a plastic phase at the oil-water interface, for the kinetics, and for the onset temperature of these processes. But further details are needed to control these processes for bottom-up manufacturing and understand their molecular mechanisms. Still unknown are the minimum concentration of the surfactant necessary to induce the processes, or competing effects in a mixture of surfactants when only one is capable of inducing shapes. Here we systematically study the effect of surfactant nature and concentration on the shape-inducing behaviour of hexadecane-in-water emulsions with both cationic (CTAB) and non-ionic (Tween, Brij) surfactants over up to five orders of magnitude of concentration. The minimum effective concentration is found approximately equal to the critical micelle concentration (CMC), or the solubility limit below the Krafft point of the surfactant. However, the emulsions show low stability at the vicinity of CMC. In a mixed surfactant experiment (Tween 60 and Tween 20), where only one (Tween 60) can induce shapes we elucidate the role of competition at the interface during mixed surfactant adsorption by varying the composition. We find that a lower bound of ~ 75% surface coverage of the shape-inducing surfactant with C14 or longer chain length is necessary for self-shaping to occur. The resulting technique produces a clear visual readout of otherwise difficult to investigate molecular events and establish basic requirements for minimum concentration and protocols to find % surface coverage to induce oil self-shaping by surfactant mixtures.