Phonon renormalization effects accompanying the 6 K anomaly in the Quantum Spin Liquid Candidate $\kappa$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$

TL;DR

This study investigates phonon renormalization effects at the 6 K anomaly in the quantum spin liquid candidate $$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$ using inelastic neutron scattering, revealing a phase transition into a valence bond solid state.

Contribution

It provides the first direct evidence of phonon damping changes associated with the 6 K anomaly, linking it to a valence bond solid phase transition.

Findings

Significant phonon damping change at $T^{*}$ for a specific mode.

Evidence supporting a phase transition into a valence bond solid state.

Phonon renormalization linked to spin-charge coupling effects.

Abstract

The low-temperature state of the quantum spin liquid candidate $\kappa$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$ emerges via an anomaly at $T^{*}\sim6$ K. Although signatures of this anomaly have been revealed in various quantities, its origin has remained unclear. Here we report inelastic neutron scattering measurements on single crystals of $\kappa$-(BEDT-TTF)$_{2}$Cu$_{2}$(CN)$_{3}$, aiming at studying phonon renormalization effects at $T^{*}$. A drastic change was observed in the phonon damping across $T^{*}$ for a breathing mode of BEDT-TTF dimers at $E=4.7$ meV. The abrupt change in the phonon damping is attributed to a phase transition into a valence bond solid state based on an effective model describing the spin-charge coupling in this dimer-Mott system.