The impact of ionic contribution to dielectric permittivity in 11CB liquid crystal and its colloids with BaTiO3 nanoparticles

TL;DR

This study investigates how ionic contributions influence dielectric permittivity in 11CB liquid crystals and their BaTiO3 colloids across various phases, revealing pretransitional effects and phase transition behaviors.

Contribution

It provides new experimental insights into ionic effects on dielectric properties and phase transitions in liquid crystal colloids, especially near critical points.

Findings

Pretransitional fluctuations are significantly affected by nanoparticles.

Strong evidence of ionic-related polarization near phase transitions.

Validation of the dielectric spectrum relation in liquid crystal nanocolloids.

Abstract

The report shows the temperature behavior of the real part of dielectric permittivity in the static (dielectric constant) and lo-frequency (LF) domains in bulk samples of 11CB and BaTiO3-based nanocolloids. The study covers the Isotropic Liquid (I), Nematic (N), Smectoc A (SmA) and Solid CRystal (Cr) phases. For each phase, the dominance of pretransitional fluctuations, significantly moderated by nanoparticles is shown. The authors consider separate focus on dielectric constant(Eps(T)) evolution in the static domain yielding mainly response from permanent dipole moments and their arrangement and in the low-frequency (LF) domain DeltaEps'(f)=Eps'(f)-Eps(where Eps'(f) is for the real part of dielectric permittivity in the LF domain).which is associated solely with ionic-related polarization mechanism. All these lead to new experimental evidence concerning I-N, N-SmA and SmA-Cr transitions.focusing on the strength and extent of pretransitional effects, critical exponents and phase transition discontinuities. The strong evidence for pretransitional effects near SmA-N transition is notable, particularly regarding DeltaEps'(f,T). Studies are supplemented by DC electric conductivity - the parameter also related to LF domain. Finally, the validity of the relation Eps'(f,T) = Af^(-3/2)+Eps (where f stands for the frequency and A is a constant parameter) often used for discussing dielectric spectra in LC compounds and its nanocollids in the LF domain, is examined.