Tracer dynamics in dense soft-colloidal suspensions: From free diffusion to hopping

TL;DR

This study uses simulations to analyze how tracer particles move in dense soft-colloidal suspensions, revealing a transition from free diffusion to hopping behavior depending on particle softness and temperature.

Contribution

It systematically investigates the impact of colloid and tracer softness on tracer dynamics near the freezing transition using dissipative particle dynamics simulations.

Findings

Tracer in ultra-soft colloids exhibits diffusive motion at long times.

Hard colloids induce hopping behavior with intermittent jumps.

Relaxation times increase with tracer hardness in ultra-soft fluids.

Abstract

Tracking of individual particle and studying their motion serves as a direct means to understand the dynamics in crowded and complex environments. In this study, the dynamics of tracer particles in the matrix of dense soft-colloidal suspensions in fluid phase is studied by means of dissipative particle dynamics simulations. By considering relatively large tracer (three times that of colloid) we systematically explore the interplay between the environment in which the tracer undergoes motion and interaction with the environment on the dynamics for temperatures close to the thermodynamic freezing transition where the effect of pair-wise interaction is significant compared to thermal energy. To this end we consider three fluid systems differing in the degree of softness (i.e., ultra-soft, intermediate, and hard) of the constituent colloidal particles, also change tracer types in the sense that we vary the degree of softness of the tracer w.r.t. colloids from ultra-soft to very hard. It is found that for tracer in ultra-soft colloidal fluid, at long times, the motion is diffusive for all tracer types, however the relaxation time (or diffusion constant) increases (or decreases) with increasing hardness of tracer at a given temperature. Interestingly, for tracer in hard colloidal fluid, the motion changes from a free diffusion (continuous trajectory) to that of hopping where there is intermittent jumps following a long period of localized vibrations and consequently displacement distribution function show higher order peaks indicating different dynamics at different time (or length) scales.