Thermodynamic Uncertainty Relations for Steady-State Thermodynamics

TL;DR

This paper develops thermodynamic uncertainty relations for excess and housekeeping entropy productions in non-equilibrium steady states, providing tools to estimate these components and a joint uncertainty bound.

Contribution

It introduces a decomposition of currents into excess and housekeeping parts, deriving uncertainty relations and a geometric interpretation for steady-state thermodynamics.

Findings

Derived bounds on excess and housekeeping entropy productions.

Established a joint uncertainty relation for the two entropy components.

Applied the theory to illustrative examples demonstrating practical estimation.

Abstract

A system can be driven out of equilibrium by both time-dependent and nonconservative forces, which gives rise to a decomposition of the dissipation into two non-negative components, called the excess and housekeeping entropy productions. We derive thermodynamic uncertainty relations for the excess and housekeeping entropy. These can be used as tools to estimate the individual components, which are in general difficult to measure directly. We introduce a decomposition of an arbitrary current into excess and housekeeping parts, which provide lower bounds on the respective entropy production. Furthermore, we also provide a geometric interpretation of the decomposition, and show that the uncertainties of the two components are not independent, but rather have to obey a joint uncertainty relation, which also yields a tighter bound on the total entropy production. We apply our results to two examples that illustrate the physical interpretation of the components of the current and how to estimate the entropy production.