Combinatorial sputter deposition of CrMnFeCoNi high entropy alloy thin films on agitated particles

TL;DR

This paper introduces a novel combinatorial sputter deposition method for uniformly coating microparticles with high entropy alloy thin films, enabling simultaneous multi-batch processing and composition gradients.

Contribution

It develops a laboratory-scale agitation technique using a piezoelectric actuator for uniform thin film coating on microparticles during sputtering.

Findings

Achieved homogeneous coating on various particle types.

Demonstrated simultaneous multi-batch coating with different materials.

Produced composition gradient films on uniform particles.

Abstract

A method for combinatorial sputter deposition of thin films on microparticles is presented. The method is developed for a laboratory-scale magnetron sputter system and uses a piezoelectric actuator to agitate the microparticles through oscillation. Custom-made components enable to agitate up to nine separate batches of particles simultaneously. Due to the agitation, the whole surface of the particles can be exposed to the sputter flux and thus can be completely covered with a thin film. By sputtering a CrMnFeCoNi high entropy alloy target, separate batches of polystyrene microspheres (500 um monodisperse diameter), Fe alloy particles (300 um mean size) and NaCl salt particles (350 um mean size) were simultaneously coated with a homogeneous thin film. In contrast, a CrMnFeCoNi thin film that was deposited on agglomerating Al particles (5 um mean size) only partially covers the surface of the particles. By co-sputtering a CrMn, an FeCo and a Ni target, nine separate batches of Al particles (25 um mean size) were coated with a CrMnFeCoNi thin film with a composition gradient. These depositions demonstrate the ability to coat different types of particles with uniform films (from elemental to multinary compositions) and to deposit films with composition gradients on uniform particles.