Theory of triangulene two-dimensional crystals

TL;DR

This paper develops a unified theoretical framework for electronic properties of 2D honeycomb lattices made from triangulene molecules, revealing diverse band structures and topological phases through combined DFT and tight-binding calculations.

Contribution

It introduces a comprehensive theory for triangulene-based 2D crystals, extending the graphene model to include internal pseudospin degrees of freedom and various electronic phases.

Findings

Discovery of graphene-like spectra in certain triangulene lattices

Identification of spin-1 Dirac electrons in specific configurations

Prediction of flat bands and topological phases in the studied systems

Abstract

Equilateral triangle-shaped graphene nanoislands with a lateral dimension of $n$ benzene rings are known as $[n]$triangulenes. Individual $[n]$triangulenes are open-shell molecules, with single-particle electronic spectra that host $n-1$ half-filled zero modes and a many-body ground state with spin $S=(n-1)/2$. The on-surface synthesis of triangulenes has been demonstrated for $n=3,4,5,7$ and the observation of a Haldane symmetry-protected topological phase has been reported in chains of $[3]$triangulenes. Here, we provide a unified theory for the electronic properties of a family of two-dimensional honeycomb lattices whose unit cell contains a pair of triangulenes with dimensions $n_a,n_b$. Combining density functional theory and tight-binding calculations, we find a wealth of half-filled narrow bands, including a graphene-like spectrum (for $n_a=n_b=2$), spin-1 Dirac electrons (for $n_a=2,n_b=3$), $p_{x,y}$-orbital physics (for $n_a=n_b=3$), as well as a gapped system with flat valence and conduction bands (for $n_a=n_b=4$). All these results are rationalized with a class of effective Hamiltonians acting on the subspace of the zero-energy states that generalize the graphene honeycomb model to the case of fermions with an internal pseudospin degree of freedom with $C_3$ symmetry.