Doping as a tuning mechanism for magneto-thermoelectric effects to improve zT in polycrystalline NbP

TL;DR

This study demonstrates how doping in polycrystalline NbP can tune magneto-thermoelectric effects, shifting optimal operating temperatures and enhancing thermoelectric efficiency, with potential for novel device applications.

Contribution

It introduces doping as a method to control magneto-thermoelectric effects in NbP, enabling improved zT at targeted temperatures for thermoelectric devices.

Findings

Large Nernst and magneto-Seebeck effects observed simultaneously.

Doping shifts the temperature of maximum thermopower.

Theoretical models confirm doping alters chemical potential and thermopower.

Abstract

Weyl semimetals combine topological and semimetallic effects, making them candidates for interesting and effective thermoelectric transport properties. Here, we present experimental results on polycrystalline NbP, demonstrating the simultaneous existence of a large Nernst effect and a large magneto-Seebeck effect, which is typically not observed in a single material at the same temperature. We compare transport results from two polycrystalline samples of NbP with previously published work, observing a shift in the temperature at which the maximum Nernst and magneto-Seebeck thermopowers occur, while still maintaining thermopowers of similar magnitude. Theoretical modeling shows how doping strongly alters both the Seebeck and Nernst magneto-thermopowers by shifting the temperature-dependent chemical potential, and the corresponding calculations provide a consistent interpretation of our results. Thus, we offer doping as a tuning mechanism for shifting magneto-thermoelectric effects to temperatures appropriate for device applications, improving zT at desirable operating temperature. Furthermore, the simultaneous presence of both a large Nernst and magneto-Seebeck thermopower is uncommon and offers unique device advantages if the thermopowers are used additively. Here, we also propose a unique thermoelectric device which would collectively harness the large Nernst and magneto-Seebeck thermopowers to greatly enhance the output and zT of conventional thermoelectric devices.