Distinguished self-adjoint extension and eigenvalues of operators with gaps. Application to Dirac-Coulomb operators

TL;DR

This paper introduces a geometric approach to defining a distinguished self-adjoint extension with a spectral gap for operators like the Dirac-Coulomb, characterizing eigenvalues within the gap under minimal assumptions.

Contribution

It provides a new geometric method to establish a self-adjoint extension with a spectral gap and eigenvalue characterization, reducing technical assumptions compared to previous approaches.

Findings

Successfully characterizes eigenvalues in the spectral gap using a min-max principle.

Applies to Dirac-Coulomb-like operators with sign-changing potentials.

Covers molecules with multiple nuclei and atomic numbers up to 137.

Abstract

We consider a linear symmetric operator in a Hilbert space that is neither bounded from above nor from below, admits a block decomposition corresponding to an orthogonal splitting of the Hilbert space and has a variational gap property associated with the block decomposition. A typical example is the Dirac-Coulomb operator defined on $C^\infty_c(\mathbb R^3\setminus\{0\}, \mathbb C^4)$. In this paper we define a distinguished self-adjoint extension with a spectral gap and characterize its eigenvalues in that gap by a min-max principle. This has been done in the past under technical conditions. Here we use a different, geometric strategy, to achieve that goal by making only minimal assumptions. Our result applied to the Dirac-Coulomb-like Hamitonians covers sign-changing potentials as well as molecules with an arbitrary number of nuclei having atomic numbers less than or equal to 137.