Tunable Ferromagnetism in LaCoO3 Epitaxial Thin Films

TL;DR

This paper demonstrates that the ferromagnetic properties of LaCoO3 epitaxial thin films, including Curie temperature and magnetization, can be significantly enhanced by altering crystallographic orientation, revealing a new method for tuning magnetic behavior.

Contribution

The study shows that changing the crystallographic orientation of LaCoO3 thin films can substantially enhance ferromagnetic properties, independent of epitaxial strain levels.

Findings

Curie temperature increased by ~18% with orientation change

Crystallographic orientation affects charge transfer and crystal-field energy

Structural symmetry control enables tunable ferromagnetism

Abstract

Ferromagnetic insulators play a crucial role in the development of low-dissipation quantum magnetic devices for spintronics. Epitaxial LaCoO3 thin film is a prominent ferromagnetic insulator, in which the robust ferromagnetic ordering emerges owing to epitaxial strain. Whereas it is evident that strong spin-lattice coupling induces ferromagnetism, the reported ferromagnetic properties of epitaxially strained LaCoO3 thin films were highly consistent. For example, even under largely modulated degree of strain, the reported Curie temperatures of epitaxially strained LaCoO3 thin films lie within 80-85 K, without much deviation. In this study, substantial enhancement (~18%) in the Curie temperature of epitaxial LaCoO3 thin films is demonstrated via crystallographic orientation dependence. By changing the crystallographic orientation of the films from (111) to (110), the crystal-field energy was reduced and the charge transfer between the Co and O orbitals was enhanced. These modifications led to a considerable enhancement of the ferromagnetic properties (including the Curie temperature and magnetization), despite the identical nominal degree of epitaxial strain. The findings of this study provide insights into facile tunability of ferromagnetic properties via structural symmetry control in LaCoO3.