Hybrid aqueous/ionic liquid electrolyte for high cycle stability and low temperature adaptability lithium-ion battery

TL;DR

This paper introduces a hybrid aqueous/ionic liquid electrolyte with a wide electrochemical window and low freezing point, enhancing lithium-ion battery stability, safety, and low-temperature performance.

Contribution

A novel hybrid electrolyte using EMIMDep additive is developed, improving cycle stability and low-temperature adaptability of lithium-ion batteries.

Findings

Electrochemical window of 2.15V achieved.

Battery retains 80% capacity after 500 cycles.

Operates at -35°C with 60% capacity retention.

Abstract

Aqueous rechargeable batteries are promising energy storage devices for the high safety, environmental friendliness, and easy assembly. However, their cycle stability and low temperature performance are limited by the narrow electrochemical stability window and the high freezing point of the aqueous electrolytes. Here, a hybrid electrolyte with a wide electrochemical window (2.15V) and a low freezing point (-60 oC) is developed by using EMIMDep as a novel additive. The hydrophobic EMIM+ accumulates on the negatively charged electrode and repels the water molecules, thus suppressing the water splitting. Meanwhile, the hydrophilic Dep- forms strong hydrogen bonds with water, thereby reducing the freezing point of the electrolyte. In addition, the hybrid 1 M LiNO3 in EMIMDep20-H2O80 electrolytes exhibit high safety and high stability due to the non-flammability, non-volatility, and low toxicity of the EMIMDep compared with other organic additives. Owing to the advantages of the aqueous/EMIMDep electrolyte, the full battery with LiTi$_2$(PO$_4$)$_3$ anode and LiMn$_2$O$_4$ cathode delivers an average voltage of 1.6 V and a specific capacity of 120 mAh/g with a capacity retention of 80% after 500 cycles at 1C. In addition, the full battery working at -35 oC delivers 60% specific capacity of that at room temperature.