Individual ion species chemical potentials in the Mean Spherical Approximation

TL;DR

This paper extends the Mean Spherical Approximation (MSA) to include individual ion species chemical potentials, providing a more complete and accurate formulation that also relaxes the assumption of strict charge neutrality.

Contribution

The authors derive additional terms for individual ion chemical potentials in MSA, improving its accuracy and applicability to near-neutral systems.

Findings

Derived a complete additive term for individual ion chemical potentials in MSA.

Showed MSA's validity extends to systems close to charge neutrality.

Demonstrated qualitative improvement over previous MSA formulations.

Abstract

The Mean Spherical Approximation (MSA) is a commonly-used thermodynamic theory for computing the energetics of ions in the primitive model (i.e., charged hard-sphere ions in a background dielectric). For the excess chemical potential, however, the early MSA formulations (which were widely adopted) only included the terms needed to compute the mean excess chemical potential (or the mean activity coefficient). Other terms for the chemical potential $\mu_i$ of individual species $i$ were not included because they sum to $0$ in the mean chemical potential. Here, we derive these terms to give a complete MSA formulation of the chemical potential. The result is a simple additive term for $\mu_i$ that we show is a qualitative improvement over the previous MSA version. In addition, our derivation shows that the MSA's assumption of global charge neutrality is not strictly necessary, so that the MSA is also valid for systems close to neutrality.