Exact time-dependent analytical solutions for entropy production rate for a system that operates in a heat bath where its temperature varies linearly in space

TL;DR

This paper derives exact time-dependent analytical solutions for entropy production and free energy in a Brownian system with spatially varying temperature, revealing differences in thermodynamic behavior compared to systems at equilibrium or with uniform temperature.

Contribution

It provides novel exact solutions for entropy and free energy dynamics in non-equilibrium systems with spatial temperature variation, extending previous models.

Findings

Entropy production and extraction rates approach steady state in both hot-cold and linearly varying temperature systems.

Free energy change varies linearly in space for systems with spatially varying temperature.

Systems with linearly varying temperature exhibit higher entropy and irreversibility than hot-cold systems.

Abstract

The nonequilibrium thermodynamics feature of a Brownian motor is investigated by obtaining exact time-dependent solutions. This in turn enables us to investigate not only the long time property (steady-state) but also the short time the behavior of the system. The general expressions for the free energy, entropy production ${\dot e}_{p}(t)$ as well as entropy extraction ${\dot h}_{d}(t)$ rates are derived for a system that is genuinely driven out of equilibrium by time-independent force as well as by spatially varying thermal background. We show that for a system that operates between hot and cold reservoirs, most of the thermodynamics quantities approach a non-equilibrium steady state in the long time limit. The change in free energy becomes minimal at a steady state. However for a system that operates in a heat bath where its temperature varies linearly in space, the entropy production and extraction rates approach a non-equilibrium steady state while the change in free energy varies linearly in space. This reveals that unlike systems at equilibrium, when systems are driven out of equilibrium, their free energy may not be minimized. The thermodynamic properties of a system that operates between the hot and cold baths are further compared and contrasted with a system that operates in a heat bath where its temperature varies linearly in space along with the reaction coordinate. We show that the entropy, entropy production, and extraction rates are considerably larger for linearly varying temperature case than a system that operates between the hot and cold baths revealing such systems are inherently irreversible. For both cases, in the presence of load or when a distinct temperature difference is retained, the entropy $S(t)$ monotonously increases with time and saturates to a constant value as $t$ further steps up.