Tuning paradigm of external stimuli driven electronic, optical, and magnetic properties in Hybrid Perovskites and Metal Organic Complexes

TL;DR

This review explores how external stimuli like pressure, temperature, and light can tune the electronic, optical, and magnetic properties of hybrid perovskites and metal organic complexes, highlighting mechanisms, experimental insights, and potential applications.

Contribution

It provides a comprehensive overview of the theoretical mechanisms and experimental literature on stimuli-induced property tuning in hybrid perovskites and metal organic complexes, with future application insights.

Findings

Stimuli induce spin transitions and optical/magnetic responses.

Hysteresis effects enable memory and optical switching.

Pressure tuning leads to piezochromic optical properties.

Abstract

We have witnessed a wide range of theoretical as well as experimental investigations to envisage external stimuli induced changes in electronic, optical, and magnetic properties in the metal organic complexes, while hybrid perovskites have recently joined this exciting league of explorations. The flexible organic linkers in such complexes are ideal for triggering not only spin transitions but also a plethora of different responses under the influence of external stimuli like pressure, temperature, and light. A diverse range of applications particularly in the field of optoelectronics, spintronics, and energy scavenging have been manifested. Hysteresis associated with light induced transitions and spin-crossover governed by pressure and temperature are promising phenomena for the design principles behind memory devices and optical switches. Pressure induced optical properties tuning or piezochromism has also emerged as one of the prominent areas in the field of hybrid perovskites. It is thus imperative to have a clear understanding of how the tuning in electronic, optical, and magnetic properties occur under various stimuli. Selectivity of the stimulus could be influential behind the maximum efficiency in the field of energy and optoelectronic research to determine in what future directions this field could be driven from the perspective of futuristic material properties. This review though primarily focuses on the theoretical aspects of understanding the different mechanisms of the phenomena, does provide a unique overview of the experimental literature too, such that relevant device applications can be considered through a future roadmap of tuning paradigm of external stimuli. It also provides an insight as to how energy and memory storage may be combined by using the principles of spin transition in metal organic complexes.