Structural, Dielectric, and Electrical Transport Properties of Al3+ Substituted Nanocrystalline Ni-Cu Spinel Ferrites Prepared Through the Sol-Gel Route

TL;DR

This study synthesizes Al3+-substituted Ni-Cu spinel ferrite nanoparticles via sol-gel method, analyzing their structural, morphological, dielectric, and electrical properties, revealing phase purity, size variation, and compositional consistency.

Contribution

It provides new insights into how Al3+ substitution affects the properties of Ni-Cu ferrite nanoparticles synthesized through sol-gel auto combustion.

Findings

Single-phase cubic spinel structure confirmed by XRD and FTIR.

Grain size slightly decreases with increased Al3+ content.

Energy dispersive X-ray analysis verifies proper elemental composition.

Abstract

In this study, a series of nanocrystalline ferrites of Ni0.7Cu0.30AlxFe2-xO4 (x=0.00 to 0.10 with a step of 0.02) has been synthesized through the sol-gel auto combustion technique. The structural, morphological, dielectric, and electrical properties of the Ni-Cu spinel ferrite nanoparticles are analyzed due to the substitution of Al3+ content. The crystalline and structural characteristics of the prepared nanoparticles (NPs) have been studied employing the x-ray diffraction (XRD) spectra and FTIR analysis. The extracted XRD patterns assure the single-phase cubic spinel structure of all samples with homogeneity and no impurity, which indicates the yielding of high crystalline NPs. A slight decrease of average grain size with increment of Al3+ content is observed in the surface morphological study carried out by the field emission scanning electron microscopy (FESEM). The studied materials are found in semi-spherical shapes, showing the multi-domain grains separated by grain boundaries with some agglomerations. The chemical composition study for the synthesized NI-Cu spinel ferrites using energy dispersive x-ray (EDX) ensures the presence of each component in appropriate proportions in each sample.