Structural lubricity of physisorbed gold clusters on graphite and its breakdown: Role of boundary conditions and contact lines

TL;DR

This study uses molecular dynamics to explore the sliding friction of gold clusters on graphite, revealing how boundary conditions influence the transition from viscous to Coulomb friction and the role of contact line dynamics.

Contribution

It demonstrates the impact of boundary conditions on frictional behavior and characterizes the instabilities associated with Coulomb friction in gold-graphite interfaces.

Findings

Velocity-insensitive Coulomb friction occurs under specific boundary conditions.

Boundary conditions significantly affect the nature of kinetic friction.

Contact line dynamics are linked to symmetry breaking and frictional instabilities.

Abstract

The sliding motion of gold slabs adsorbed on a graphite substrate is simulated using molecular-dynamics. The central quantity of interest is the mean lateral force, i.e., the kinetic friction rather than the maximum lateral forces, which correlate with the static friction. For most set-ups, we find Stokesian damping to resist sliding. However, velocity-insensitive (Coulomb) friction is observed for finite-width slabs sliding parallel to the armchair direction if the bottommost layer of the three graphite layers is kept at zero stress rather than at zero displacement. Although the resulting kinetic friction remain much below the noise produced by the erratic fluctuations of (conservative) forces typical for structurally lubric contacts, the nature of the instabilities leading to Coulomb friction could be characterized as quasi-discontinuous dynamics of the Moir\'e patterns formed by the normal displacements near a propagating contact line. It appears that the interaction of the graphite with the second gold layer is responsible for the symmetry breaking occurring in the interface when a contact line moves parallel to the armchair rather than to the zigzag direction.