Frequency chirped Fourier-Transform spectroscopy

TL;DR

This paper introduces a novel Fourier-transform spectrometer using rotational mirror motion, enabling high spectral resolution on sub-millisecond timescales and combining dual-comb spectroscopy advantages with a single laser source.

Contribution

It presents a rotational FT spectrometer that decouples spectral and temporal resolution, allowing high-speed, high-resolution measurements without dispersive elements, and integrates dual-comb spectroscopy with a single source.

Findings

Achieves 0.5 cm${}^{-1}$ spectral resolution on sub-ms timescales.

Enables dual-comb spectroscopy with a single quantum cascade laser.

Supports large optical bandwidth from visible to THz frequencies.

Abstract

Fast (sub-second) spectroscopy with high spectral resolution is of vital importance for revealing quantum chemistry kinetics of complex chemical and biological reactions. Fourier transform (FT) spectrometers can achieve high spectral resolution and operate at hundreds of ms time scales in rapid-scan mode. However, the linear translation of a scanning mirror imposes stringent time-resolution limitations to these systems, which makes simultaneous high spectral and temporal resolution impossible. Here, we demonstrate an FT spectrometer whose operational principle is based on continuous rotational, rather than linear, motion of the scanning mirror, decoupling the spectral resolution from the temporal one. This enables 0.5 cm${}^{-1}$ resolution on sub-ms time scales. Furthermore, we show that such rotational FT spectrometers can perform dual-comb spectroscopy with a single comb source, since the Doppler-shifted version of the comb serves as the second comb. In this way, we combine the advantages of dual-comb and FT spectroscopy using a single quantum cascade laser frequency comb as a light source. Our technique does not require any diffractive or dispersive optical elements and hence preserve the Jacquinot's-, Fellgett's-, and Connes'-advantages of FT spectrometers. The system supports a large optical bandwidth from visible to THz frequencies. The combination of a rotational delay line with collimated coherent or non-coherent light sources pave the way for FT spectrometers in applications where high speed, large optical bandwidth, and high spectral resolution are desired.