Flow-electrode capacitive deionization enables continuous and energy-efficient brine concentration

TL;DR

Flow-electrode capacitive deionization (FCDI) is demonstrated as an energy-efficient, continuous method for high-concentration brine treatment and salt recovery, outperforming traditional technologies in energy consumption.

Contribution

This paper introduces the application of continuous FCDI for high salinity brine treatment, achieving high salt concentrations and significant energy reduction.

Findings

Achieved up to 291.5 g/L NaCl concentration in product stream.

Reduced energy demand by over 70% with multiple cell pairs.

FCDI shows potential to compete with established brine treatment technologies.

Abstract

Many industrial and agricultural applications require the treatment of water streams containing high concentrations of ionic species for closing material cycles. High concentration factors are often desired, but hard to achieve with established thermal or membrane-based water treatment technologies at low energy consumptions. Capacitive deionization processes are normally assumed as relevant for the treatment of low salinity solutions only. Flow-electrode capacitive deionization (FCDI), on the other hand, is an electrically driven water desalination technology, which allows the continuous desalination and concentration of saline water streams even at elevated salinities. Ions are adsorbed electrostatically in pumpable carbon flow electrodes, which enable a range of new process designs. In this article, it is shown that continuously operated FCDI systems can be applied for the treatment of salt brines. Concentrations of up to 291.5~g/L NaCl were reached in the concentrate product stream. Based on this, FCDI is a promising technology for brine treatment and salt recovery. Additionally, a reduction of the energy demand by more than 70% is demonstrated by introducing multiple cell pairs into a continuous FCDI system. While the economic feasibility is not investigated here, the results show that FCDI systems may compete with established technologies regarding their energy demand.