Quantum fluctuations approach to the nonequilibrium $GW$ approximation

TL;DR

This paper introduces a quantum fluctuations approach to the nonequilibrium $GW$ approximation, deriving stochastic variants that simplify calculations while maintaining accuracy in weak coupling regimes.

Contribution

It develops a new quantum fluctuations framework and stochastic $GW$ methods, providing an alternative to traditional NEGF approaches for nonequilibrium many-body systems.

Findings

Stochastic $GW$ and SPA are equivalent to single-time $GW$ in weak coupling.

The approach allows replacing ensemble averages with semiclassical averages.

Numerical tests show linear scaling similar to G1-G2 scheme.

Abstract

The quantum dynamics of fermionic or bosonic many-body systems following external excitation can be successfully studied using two-time nonequilibrium Green's functions (NEGF) or single-time reduced density matrix methods. Approximations are introduced via a proper choice of the many-particle self-energy or decoupling of the BBGKY hierarchy. These approximations are based on Feynman's diagram approaches or on cluster expansions into single-particle and correlation operators. Here, we develop a different approach where, instead of equations of motion for the many-particle NEGF (or density operators), single-time equations for the correlation functions of fluctuations are analyzed. We present a derivation of the first two equations of the alternative hierarchy of fluctuations and discuss possible decoupling approximations. In particular, we derive the polarization approximation (PA) which is shown to be equivalent to the single-time version [following by applying the generalized Kadanoff-Baym ansatz (GKBA)] of the nonequilibrium $GW$ approximation with exchange effects of NEGF theory, for weak coupling. The main advantage of the quantum fluctuations approach is that the standard ensemble average can be replaced by a semiclassical average over different initial realizations, as was demonstrated before by Lacroix and co-workers [see e.g. D. Lacroix et al., Phys. Rev. B, 2014, 90, 125112]. Here, we introduce the stochastic $GW$ (SGW) approximation and the stochastic polarization approximation (SPA) which are demonstrated to be equivalent to the single-time $GW$ approximation without and with exchange, respectively, in the weak coupling limit. Our numerical tests confirm that our approach has the same favorable linear scaling with the computation time as the recently developed G1-G2 scheme [Schluenzen et al., Phys. Rev. Lett., 2020, 124, 076601].