Near-field radiative heat transfer between irregularly shaped dielectric particles modeled with the discrete system Green's function method

TL;DR

This paper models near-field radiative heat transfer between irregular dielectric particles using the discrete system Green's function method, revealing how irregularity affects conductance and spectral properties at nanoscale separations.

Contribution

Introduces and verifies the DSGF method for irregular particles, demonstrating its effectiveness in modeling NFRHT and analyzing the impact of particle shape on heat transfer and spectral features.

Findings

Irregular particles reduce total conductance at small separations.

At larger separations, conductance converges to that of perfect spheres.

Irregularity causes damping and broadening of resonances.

Abstract

Near-field radiative heat transfer (NFRHT) between irregularly shaped dielectric particles made of SiO2 and morphology characterized by Gaussian random spheres is studied. Particles are modeled using the discrete system Green's function (DSGF) approach, which is a volume integral numerical method based on fluctuational electrodynamics. This method is applicable to finite, three-dimensional objects, and all system interactions are defined independent of thermal excitation by a generalized system Green's function. The DSGF method is deemed suitable to model NFRHT between irregularly shaped particles after verification against the analytical solution for chains of two and three SiO2 spheres. The NFRHT results reveal that geometric irregularity in particles leads to a reduction of the total conductance from that of comparable perfect spheres at vacuum separation distances smaller than the particle size, a regime in which NFRHT is a surface phenomenon. At vacuum separation distances larger than the particle size, NFRHT becomes a volumetric process, and the total conductance between irregularly shaped particles converges to that of comparable perfect spheres. Spectral analysis reveals, however, that particle irregularity leads to damping and broadening of resonances at all separation distances, thereby highlighting the importance of the DSGF method for spectral engineering in the near field. The reduced spectral coherence when particle size is larger than the vacuum separation distance is attributed to coupling of surface phonon-polaritons within the randomly generated, distorted particle features. For particle size smaller than the vacuum separation distance, resonance broadening and damping is linked with the multiple localized surface phonon modes supported by the composite spherical harmonic morphologies of the Gaussian random spheres.