Plasmonic and photonic enhancement of chiral near fields

TL;DR

This paper reviews recent advances in plasmonic and photonic nanostructures that generate enhanced chiral near fields, significantly improving chiral molecule detection and related applications.

Contribution

It provides a comprehensive overview of the principles, developments, and applications of chiral near field enhancement using nanostructures, highlighting recent progress and challenges.

Findings

Enhanced circular dichroism in chiral molecules

Generation of superchiral near fields via nanostructures

Applications in chiral sensing and optical manipulation

Abstract

A chiral near field with a highly contorted electromagnetic field builds a bridge to match the chiral molecules and light wavelengths with large size differences. It significantly enhances the circular dichroism of chiral molecules and has great prospects in chirality sensing, detection, trapping, and other chirality-related applications. Surface plasmons feature outstanding light-trapping and electromagnetic-field-concentrating abilities. Plasmonic chiral nanostructures facilitate light manipulation to generate superchiral near fields. Meanwhile, the nanophotonic structures have attracted significant interest to obtain strong chiral fields due to their unique electromagnetic resonant properties. During the interaction of light and chiral materials, the chiral near field not only bridges the light and chiral molecules but is also responsible for the optical activities. This paper reviews state-of-the-art studies on chiral near field enhancement using plasmonic and photonic nanostructures. We review the principle of chiral electromagnetic fields and the development of plasmonic and photonic nanostructures for near field enhancement. The properties and applications of enhanced chiral near fields for chiral molecule detection, spin-orbit angular interaction, and the generation of the chiral optical force are examined. Finally, we discuss current challenges and provide a brief outlook of this field.