Active-carbon based supercapacitors with Au colloids: the case for placing the colloids at the electrolyte/electrode interface

TL;DR

This study demonstrates that placing negatively charged gold colloids at the electrolyte/electrode interface significantly enhances supercapacitor capacitance, with a tenfold increase observed using minimal AuNPs and specific electrolyte conditions.

Contribution

It introduces a novel method of deploying functionalized Au colloids at the electrolyte/electrode interface to substantially boost supercapacitor capacitance.

Findings

Capacitance increased by a factor of 10 with AuNP addition.

Capacitance enhancement remained significant (~3x) across different electrolytes.

Strong adhesion of AuNPs to electrode surface was observed.

Abstract

Supercapacitors (S-C) are short-term energy storage elements that find many applications, e.g., electronic charging devices and suppressors of power fluctuations in grids that are interfaced with sustainable sources. The capacitance of an ordinary capacitor increases when dispersing metallic colloids in its dielectric. A similar strategy for S-C means a deployment of nano-scale metal colloids (in our case, Au nano particles, or AuNPs) at the very narrow interface between an electrolyte and the porous electrode (here, active-carbon film on a grafoil current collector). This is achieved by making the ligand that is coating the AuNPs negatively charged. We demonstrated a very large specific capacitance increase with a minute addition of functionalized AuNPs to the slurry. For example, C-V data at a scan rate of 20 mV/s indicated a specific capacitance amplification by a factor of 10 when 30 micro-g of AuNPs were incorporated with 200 mg of active carbon while using a 1 M Na2SO4 electrolyte and a 5% cellulose acetate butyrate as a binder. We make the case that the adhesion of the AuNPs to the surface of the electrode was strong: upon replacing the electrolyte, from 1 M Na2SO4 to 1 M KOH and retaining the same set of electrodes, the enhancement capacitance factor decreased as compared to 1 M Na2SO4 electrolyte but remained large, ~3, as determined by C-V traces at the same scan rate of 20 mV/s.