Transference number in polymer electrolytes: mind the reference-frame gap

TL;DR

This paper highlights the significance of the reference frame in accurately determining transference numbers in polymer electrolytes, demonstrating that proper RF transformation aligns experimental and simulation results and clarifies the origins of negative transference numbers.

Contribution

It introduces the importance of reference frame transformation in transport coefficient analysis and clarifies the molecular origins of negative transference numbers in polymer electrolytes.

Findings

Proper RF transformation improves agreement between experiment and simulation.

Anion mass and correlation are key to negative transference numbers.

Ion aggregates are less influential than previously thought.

Abstract

The transport coefficients, in particular the transference number, of electrolyte solutions are important design parameters for electrochemical energy storage devices. Recent observation of negative transference numbers in PEO-LiTFSI under certain conditions has generated much discussion about its molecular origins, by both experimental and theoretical means. However, one overlooked factor in these efforts is the importance of the reference frame (RF). This creates a non-negligible gap when comparing experiment and simulation, because the fluxes in the experimental measurements of transport coefficients and in the linear response theory used in the molecular dynamics simulation are defined in different RFs. In this work, we show that by applying a proper RF transformation, a much improved agreement between experimental and simulation results can be achieved. Moreover, it is revealed that the anion mass and the anion-anion correlation, rather than ion aggregates, play a crucial role for the reported negative transference numbers.