Signature of electromagnetic quantum fluctuations in exciton physics

TL;DR

This paper demonstrates that electromagnetic quantum fluctuations cause a measurable blue-shift in bright excitons in semiconductors, revealing their signature through both Coulomb and photon-mediated virtual processes, and predicts long-lived excitons have minimal bright-dark splitting.

Contribution

It uncovers the electromagnetic quantum fluctuation signature in exciton physics, highlighting the roles of both Coulomb and virtual photon processes in exciton energy shifts.

Findings

Bright excitons experience a universal blue-shift due to quantum fluctuations.

Transverse virtual photons contribute alongside Coulomb processes to the shift.

Long-lived excitons are predicted to have a small bright-dark energy splitting.

Abstract

Quantum fluctuations of the electromagnetic field are known to produce the atomic Lamb shift. We here reveal their iconic signature in semiconductor physics, through the blue-shift they produce to optically bright excitons, thus lifting the energy of these excitons above their dark counterparts. The electromagnetic field here acts in its full complexity: in addition to the longitudinal part via interband \textit{virtual Coulomb} processes, the transverse part -- which has been missed up to now -- also acts via resonant and nonresonant \textit{virtual photons}. These two parts beautifully combine to produce a bright exciton blue-shift independent of the exciton wave-vector direction. Our work readily leads to a striking prediction: long-lived excitons must have a small bright-dark splitting. Although the analogy between exciton and hydrogen atom could lead us to see the bright exciton shift as a Lamb shift, this is not fully so: the atom shift entirely comes from virtual photons, whereas the Coulomb interaction also contributes to the exciton shift through the so-called "electron-hole exchange".