Layer coupling between solutal and thermal convection in liquid metal batteries

TL;DR

This paper investigates the interactions between solutal and thermal convection in liquid metal batteries, revealing how flow coupling affects mass transfer and operation depending on layer geometry and mode of operation.

Contribution

It provides the first detailed analysis of flow coupling between layers in LMBs, highlighting the different behaviors of solutal and thermal convection.

Findings

Solutal convection appears before thermal convection.

Thermal convection depends on layer thickness and geometry.

Solutal flow can influence adjacent layers, unlike thermal flow.

Abstract

For longer than one decade, liquid metal batteries (LMBs) are developed with the primary aim to provide economic stationary energy storage. Featuring two liquid metal electrodes separated by a molten salt electrolyte, LMBs operate at elevated temperature as simple concentration cells. Therefore, efficient mass transfer is a basic prerequisite for their economic operation. Understanding these mechanisms cannot be limited at the single layer level. With this motivation, the effects of solutal- and thermally-driven flow are studied, as well as the flow coupling between the three liquid layers of the cell. It is shown that solutal convection appears first and thermal convection much later. While the presence of solutal flow depends on the mode of operation (charge or discharge), the occurrence of thermal convection is dictated by the geometry (thickness of layers). The coupling of the flow phenomena between the layers is intriguing: while thermal convection is confined to its area of origin, i.e. the electrolyte, solutal convection is able to drive flow in the positive electrode and in the electrolyte.