Surface modification of fly ash by mechano-chemical treatment

TL;DR

This study investigates how mechano-chemical treatment modifies fly ash surfaces, affecting particle size, morphology, and ion dissolubility, with implications for sustainable geopolymer production.

Contribution

It provides a systematic analysis of surface modifications of fly ash via mechano-chemical treatment, introducing a model linking grinding and activation effects to structural changes.

Findings

Mechano-chemical treatment alters fly ash surface morphology.

Dissolution of Si and Al ions is affected by treatment time.

A recombination model explains the effects of grinding and activation.

Abstract

Fly ash (FA), as an industry by-product has attracted much attention as a suitable supplier of silicon (Si) and aluminum (Al) in preparation of geopolymer for the sustainable environment and material science applications. Here, the effect of mechano-chemical (MC) treatment for surface modification of FA powder was systemically investigated by analyzing the size, surface morphology, crystal structure and dissolubility of Si and Al ions in alkali solutions. The dissolution dynamic as a function of MC treatment time is discussed in details and concluded with a recombination model of "grinding effect" and "activation effect", which can be well correlated with the change of surface morphology and crystal structure, respectively.