Phase Separation and Ripening in a Viscoelastic Gel

TL;DR

This paper investigates phase separation in viscoelastic gels, revealing a new domain growth regime with algebraic ripening that depends on the material's viscoelastic properties, differing from classical Ostwald ripening.

Contribution

It introduces a novel domain growth regime in viscoelastic materials, characterized by an algebraic ripening exponent influenced by viscoelastic relaxation.

Findings

Domain size increases algebraically with time in viscoelastic gels.

For Maxwell materials, the ripening exponent is exactly 1.

The theory applies to systems with arbitrary power-law relaxation behaviors.

Abstract

The process of phase separation in elastic solids and viscous fluids is of fundamental importance to the stability and function of soft materials. We explore the dynamics of phase separation and domain growth in a viscoelastic material such as a polymer gel. Using analytical theory and Monte Carlo simulations we report a new domain growth regime, in which the domain size increases algebraically with a ripening exponent $\alpha$ that depends on the viscoelastic properties of the material. For a prototypical Maxwell material, we obtain $\alpha=1$, which is markedly different from the well-known Ostwald ripening process with $\alpha=1/3$. We generalize our theory to systems with arbitrary power-law relaxation behavior and discuss our findings in the context of the long-term stability of materials as well as recent experimental results on phase separation in cross-linked networks and cytoskeleton.