Template-assisted growth of silver nanowires by electrodeposition

TL;DR

This study investigates the kinetics of silver nanowire growth within anodic aluminium oxide templates via electrodeposition, analyzing how various parameters influence wire length and growth efficiency.

Contribution

It provides a systematic analysis of electrodeposition parameters affecting silver nanowire growth in AAO templates, including pore modification and process optimization.

Findings

Lower current increases wire length.

Higher temperature enhances deposition efficiency.

Linear growth observed over time.

Abstract

Template-assisted synthesis is a facile way of growing various one-dimensional nanostructures. Among various nanoporous templates, anodic aluminium oxide (AAO) is most commonly used. In this work, the kinetics of silver nanowire growth by electrodeposition in AAO templates was investigated. The AAO templates were fabricated using the standard two-step anodisation process. The geometrical features of the fabricated templates, such as pore diameter (55 nm), interpore distance (115 nm), wall thickness (27 nm), porosity (19.87 %), and pore density were obtained using scanning electron microscopy. The oxide layer at the bottom of the pores was modified by the barrier layer thinning process and chemical etching in order to facilitate uniform metal deposition. This was followed by pore widening to increase the diameter of the pores to 65 nm to enhance deposition. Interpore distance increased to 119.8 nm and wall thickness remained almost constant at 27.7 nm. Silver was deposited using conventional electrodeposition in constant current mode. Deposition parameters such as time, current, solution concentration, and temperature were systematically investigated. For each deposition, the efficiency of the process was calculated by considering the filling fraction of the pores and the average length of the wires, all of which were measured from the SEM images. A linear growth versus time was observed within the parameter range. From the experiments, it was observed that decreasing the current, increasing the deposition temperature, and depositing for longer duration increased the average length of the nanowires. The use of electrodeposition to grow metallic nanowires can be extended to other pure metal and alloy systems.