Steam Degradation of Ytterbium Disilicate Environmental Barrier Coatings: Effect of Composition, Microstructure and Temperature

TL;DR

This study investigates how steam exposure affects ytterbium disilicate coatings used as environmental barriers in high-temperature environments, revealing microstructural changes and impurity interactions that impact coating durability.

Contribution

It provides new insights into the degradation mechanisms of Yb2Si2O7 coatings under steam, highlighting the effects of composition, microstructure, and temperature on their stability.

Findings

Yb2SiO5 depletion near the surface after steam exposure

Formation of ytterbium garnet (Yb3Al5O12) due to impurities

Higher porosity coatings showed less garnet formation

Abstract

Recession of environmental barrier coatings (EBC) in environments containing steam is a pressing concern that requires further research before their implementation in gas turbine engines can be realized. In this work, free-standing plasma sprayed Yb2Si2O7 coatings were exposed to flowing steam at 1350 {\deg}C and 1400 {\deg}C for 96 h. Three samples were investigated, one coating with a low porosity level (< 3 %) and 1 wt.% Al2O3 representing traditional EBCs; and two coatings with higher porosity levels (~20 %) representing abradable EBCs. Phase composition and microstructural evolution were studied in order to reveal the underlying mechanism for the interaction between high temperature steam and ytterbium disilicate. The results show depletion of Yb2SiO5 near the surface and formation of ytterbium garnet (Yb3Al5O12) on top of all three coatings due to the reaction with gaseous Al-containing impurities coming from the alumina furnace tubes. The 1 wt.% Al2O3 added to the EBC sample exacerbated the formation of garnet at 1400 {\deg}C compared to the abradable samples, which presented lower quantities of garnet. Additionally, inter-splat boundaries were visible after exposure, indicating preferential ingress of gaseous Al-containing impurities through the splat boundaries