Photochemical Synthesis of P-S-H Ternary Hydride at High Pressures

TL;DR

This paper reports the synthesis of a P-S-H ternary hydride at high pressures and room temperature using photochemical reactions, highlighting its potential as a near-room-temperature superconductor.

Contribution

First synthesis of P-S-H ternary hydride via photochemical reaction at high pressures and room temperature, with structural insights and phase transition observations.

Findings

P-S-H synthesized at 0.9 GPa and 4.6 GPa

Persisted up to 35.6 GPa with phase transitions

Potential candidate for near-room-temperature superconductivity

Abstract

The recent discovery of room temperature superconductivity (283 K) in carbonaceous sulfur hydride (C-S-H) has attracted lots of interests in ternary hydrogen rich materials. In this report, ternary hydride P-S-H has been synthesized through photochemical reaction from elemental sulfur (S), phosphorus (P) and molecular hydrogen (H2) at high pressures and room temperature. The Raman spectroscopy under pressure shows that H2S and PH3 compounds are synthesized after laser heating at 0.9 GPa and a ternary van der Waals compound P-S-H is synthesized with a further compression to 4.6 GPa. The P-S-H compound is probably a mixed alloy of PH3 and (H2S)2H2 with a guest-host structure similar to the C-S-H system. The ternary hydride can persist up to 35.6 GPa at least and shows two phase transitions at approximately 23.6 GPa and 32.8 GPa, respectively. The P-S-H ternary hydride in this report is a competitive candidate for new hydride superconductors with near room-temperature transitions.